Synthesis and solid state structure of a hydrazone-disulfide macrocycle and its dynamic covalent ring-opening under acidic and basic conditions.
نویسندگان
چکیده
The synthesis and characterisation, including solid state structure, of a macrocycle containing both a hydrazone and a disulfide linkage is described. Selective ring-opening of the macrocycle under thermodynamic control could be achieved at either the disulfide or the hydrazone linkage by applying mutually exclusive sets of reaction conditions.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 8 20 شماره
صفحات -
تاریخ انتشار 2010